Heats of Immersion of Silica-alumina in Nonaqueous Solvents
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چکیده
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Water in nonaqueous solvents*
The possibility and usefulness of sinple liquid models is reported. The importance of van der Waals forces for liquid water and aqueous solutions is discussed and compared with the solubility of water in nonpolar solvents and as well as of nonpolar solvents in water. Both systems could be understood as equilibrium of few water monomers. The network of H-bonded water molecules seems to be less i...
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Subtilisin and alpha-chymotrypsin vigorously act as catalysts in a variety of dry organic solvents. Enzymatic transesterifications in organic solvents follow Michaelis-Menten kinetics, and the values of V/Km roughly correlate with solvent's hydrophobicity. The amount of water required by chymotrypsin and subtilisin for catalysis in organic solvents is much less than needed to form a monolayer o...
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Introduction Literature survey Experimental • • • • Environmental chamber Electrochemical test procedure Preparation of solutions Results and discussion Characterization tests Reduction of other metals Anodic dissolution of Ti • • • • Ti reduction in DMF Ti reduction in DMSO Ti reduction in other solvents Conclusions • References CONTENTS
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Heats of immersion of alkali and alkaline earth metaphosphates in some aromatic hydrocarbons were measured with a twin microcalorimeter to investigate the interaction of the interfaces between the phosphates and the hydrocarbons. The heats of immersion in benzene for the phosphates with long chains were lower than those for the phosphates with short chains. The dependence of heat of immersion o...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1971
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.44.2107